Richard Branson's Rail Group has been running the InterCity West Coast franchise since 1997.
Mick Cash, general secretary of the union, said passengers have "had enough of being ripped off by the private rail companies' profiteering".
The cap on regulated fare increases will be announced on Wednesday.
Vincent Peone, from New York, was rebooked onto the empty flight after his original journey was cancelled.
The Rail Delivery Group (RDG) announced today that it has reached an agreement with Eurail after renewing talks.
LNER have reconnected destinations such as Inverness, Edinburgh and York by shunning the RDG decision.
A total of more than £950,000 has been paid out by Network Rail for 290 claims over the past five years for slips, trips and falls.
"Either this shows the true Little Englander nature of the Tories, or how out of touch the rail companies are with the people. Or both."
SNP MEP Alyn Smith said the move was "so sad".
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